Supercritical CO₂ – Advances in Green Chemistry

General Overview
- Replacement of conventional solvents with greener alternatives.
- Enhancement of mass transfer processes in reaction systems.
- Improvement of reaction efficiency and selectivity, while minimizing overall energy consumption.
- Simultaneous utilization of CO₂ as a reactant in certain chemical processes.
Physical and Chemical Characteristics
- Low surface tension.
- High molecular mobility.
- Low viscosity and high diffusivity.
- Density comparable to that of liquids.
- Solvent power easily tunable by adjusting temperature and pressure.
- Facilitates product separation, prolongs catalyst lifetime, enables catalyst recovery and reuse.
Environmental and Operational Advantages
- Abundant and inexpensive source.
- Inert and non-reactive toward most target compounds.
- Nonflammable and does not support combustion.
- Environmentally friendly – no emission of toxic or polluting substances.
- Nontoxic to humans and non-corrosive to equipment.
- Efficient solvent for solid and liquid organic compounds.
- Completely vaporizes without leaving harmful residues.
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